Silylium ion migration dominated hydroamidation of siloxy-alkynes

The mechanism of silver-catalyzed hydroamidation of siloxy-alkynes reaction remains controversial. Using density functional theory (DFT), we revealed that the reaction takes place through a silylium ion migration mediated hydroamination (SMH) pathway. The SMH pathway goes through two steps, the firs...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Heng-Ding, Jiang, Ling, Fan, Hong-Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9814853/
https://www.ncbi.nlm.nih.gov/pubmed/36697660
http://dx.doi.org/10.1038/s42004-022-00751-y

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9814853/
https://www.ncbi.nlm.nih.gov/pubmed/36697660
http://dx.doi.org/10.1038/s42004-022-00751-y

Ejemplares similares