Cargando…
Infrared characterization of formation and resonance stabilization of the Criegee intermediate methyl vinyl ketone oxide
Methyl vinyl ketone oxide (MVKO) is an important Criegee intermediate in the ozonolysis of isoprene. MVKO is resonance stabilized by its allyl moiety, but no spectral characterization of this stabilization was reported to date. In this study, we photolyzed a mixture of 1,3-diiodo-but-2-ene and O(2)...
| Autores principales: | , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2021
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9814936/ https://www.ncbi.nlm.nih.gov/pubmed/36697539 http://dx.doi.org/10.1038/s42004-020-00447-1 |