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Infrared characterization of formation and resonance stabilization of the Criegee intermediate methyl vinyl ketone oxide

Methyl vinyl ketone oxide (MVKO) is an important Criegee intermediate in the ozonolysis of isoprene. MVKO is resonance stabilized by its allyl moiety, but no spectral characterization of this stabilization was reported to date. In this study, we photolyzed a mixture of 1,3-diiodo-but-2-ene and O(2)...

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Detalles Bibliográficos
Autores principales:	Chung, Chen-An, Lee, Yuan-Pern
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group UK 2021
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9814936/ https://www.ncbi.nlm.nih.gov/pubmed/36697539 http://dx.doi.org/10.1038/s42004-020-00447-1

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