Change in the Electronic Structure of the Cobalt(II) Ion in a One-Dimensional Polymer with Flexible Linkers Induced by a Structural Phase Transition †

A new 1D-coordination polymer [Co(Piv)(2)(NH(2)(CH(2))(6)NH(2))](n) (1, Piv is Me(3)CCO(2)(−) anion) was obtained, the mononuclear fragments {Co(O(2)CR)(2)} within which are linked by μ-bridged molecules of hexamethylenediamine (NH(2)(CH(2))(6)NH(2)). For this compound, two different monoclinic C2/c...

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Detalles Bibliográficos
Autores principales: Yambulatov, Dmitriy S., Voronina, Julia K., Goloveshkin, Alexander S., Svetogorov, Roman D., Veber, Sergey L., Efimov, Nikolay N., Matyukhina, Anna K., Nikolaevskii, Stanislav A., Eremenko, Igor L., Kiskin, Mikhail A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9820815/
https://www.ncbi.nlm.nih.gov/pubmed/36613658
http://dx.doi.org/10.3390/ijms24010215

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9820815/
https://www.ncbi.nlm.nih.gov/pubmed/36613658
http://dx.doi.org/10.3390/ijms24010215

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