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Change in the Electronic Structure of the Cobalt(II) Ion in a One-Dimensional Polymer with Flexible Linkers Induced by a Structural Phase Transition †
A new 1D-coordination polymer [Co(Piv)(2)(NH(2)(CH(2))(6)NH(2))](n) (1, Piv is Me(3)CCO(2)(−) anion) was obtained, the mononuclear fragments {Co(O(2)CR)(2)} within which are linked by μ-bridged molecules of hexamethylenediamine (NH(2)(CH(2))(6)NH(2)). For this compound, two different monoclinic C2/c...
| Autores principales: | , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9820815/ https://www.ncbi.nlm.nih.gov/pubmed/36613658 http://dx.doi.org/10.3390/ijms24010215 |