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Expanded Ligands Based upon Iron(II) Coordination Compounds of Asymmetrical Bis(terpyridine) Domains

The synthesis and characterization of two tritopic ligands containing a 2,2′:6′,2″-terpyridine (tpy) metal binding domain and either a 3,2′:6′,3″- or a 4,2′:6′,4″-tpy domain are detailed. The synthetic routes to these ligands involved the [Pd(dppf)Cl(2)]-catalyzed coupling of a boronic ester-functio...

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Detalles Bibliográficos
Autores principales: Rocco, Dalila, Prescimone, Alessandro, Housecroft, Catherine E., Constable, Edwin C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9822043/
https://www.ncbi.nlm.nih.gov/pubmed/36615277
http://dx.doi.org/10.3390/molecules28010082