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Conjugative Stabilization versus Anchimeric Assistance in Carbocations
In this study, an old concept of anchimeric assistance is viewed from a different angle. Primary cations with two different heteroatomic substituents in the α-position to the cationic carbon atom CHXY–CH(2)(+) (X, Y = Me(2)N, MeO, Me(3)Si, Me(2)P, MeS, MeS, Br) can be stabilized by the migration of...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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MDPI
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9822469/ https://www.ncbi.nlm.nih.gov/pubmed/36615233 http://dx.doi.org/10.3390/molecules28010038 |