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Unravelling the Role of the Pentafluoroorthotellurate Group as a Ligand in Nickel Chemistry

The pentafluoroorthotellurate group (teflate, OTeF(5)) is able to form species, for which only the fluoride analogues are known. Despite nickel fluorides being widely investigated, nickel teflates have remained elusive for decades. By reaction of [NiCl(4)](2−) and neat ClOTeF(5), we have synthesized...

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Detalles Bibliográficos
Autores principales: Pérez‐Bitrián, Alberto, Hoffmann, Kurt F., Krause, Konstantin B., Thiele, Günther, Limberg, Christian, Riedel, Sebastian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9825845/
https://www.ncbi.nlm.nih.gov/pubmed/35851723
http://dx.doi.org/10.1002/chem.202202016