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Fusion of Aza‐ and Oxadiborepins with Furans in a Reversible Ring‐Opening Process Furnishes Versatile Building Blocks for Extended π‐Conjugated Materials

A modular synthesis of both difurooxa‐ and difuroazadiborepins from a common precursor is demonstrated. Starting from 2,2′‐bifuran, after protection of the positions 5 and 5’ with bulky silyl groups, formation of the novel polycycles proceeds through opening of the furan rings to a dialkyne and subs...

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Detalles Bibliográficos
Autores principales: Bachmann, Jonas, Helbig, Andreas, Crumbach, Merian, Krummenacher, Ivo, Braunschweig, Holger, Helten, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9825880/
https://www.ncbi.nlm.nih.gov/pubmed/35943830
http://dx.doi.org/10.1002/chem.202202455