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Fusion of Aza‐ and Oxadiborepins with Furans in a Reversible Ring‐Opening Process Furnishes Versatile Building Blocks for Extended π‐Conjugated Materials
A modular synthesis of both difurooxa‐ and difuroazadiborepins from a common precursor is demonstrated. Starting from 2,2′‐bifuran, after protection of the positions 5 and 5’ with bulky silyl groups, formation of the novel polycycles proceeds through opening of the furan rings to a dialkyne and subs...
Autores principales: | Bachmann, Jonas, Helbig, Andreas, Crumbach, Merian, Krummenacher, Ivo, Braunschweig, Holger, Helten, Holger |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9825880/ https://www.ncbi.nlm.nih.gov/pubmed/35943830 http://dx.doi.org/10.1002/chem.202202455 |
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