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Competing C‐4 and C‐5‐Acyl Stabilization of Uronic Acid Glycosyl Cations

Uronic acids are carbohydrates carrying a terminal carboxylic acid and have a unique reactivity in stereoselective glycosylation reactions. Herein, the competing intramolecular stabilization of uronic acid cations by the C‐5 carboxylic acid or the C‐4 acetyl group was studied with infrared ion spect...

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Detalles Bibliográficos
Autores principales: Elferink, Hidde, Remmerswaal, Wouter A., Houthuijs, Kas J., Jansen, Oscar, Hansen, Thomas, Rijs, Anouk M., Berden, Giel, Martens, Jonathan, Oomens, Jos, Codée, Jeroen D. C., Boltje, Thomas J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9825916/
https://www.ncbi.nlm.nih.gov/pubmed/35959853
http://dx.doi.org/10.1002/chem.202201724