Diastereo‐ and Enantioselective Inverse‐Electron‐Demand Diels–Alder Cycloaddition between 2‐Pyrones and Acyclic Enol Ethers

A broadly applicable diastereo‐ and enantioselective inverse‐electron‐demand Diels–Alder reaction of 2‐pyrones and acyclic enol ethers is reported herein. Using a copper(II)‐BOX catalytic system, bridged bicyclic lactones are obtained in very high yields (up to 99 % yield) and enantioselectivities (...

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Detalles Bibliográficos
Autores principales: Huang, Guanghao, Guillot, Régis, Kouklovsky, Cyrille, Maryasin, Boris, de la Torre, Aurélien
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9826153/
https://www.ncbi.nlm.nih.gov/pubmed/36040131
http://dx.doi.org/10.1002/anie.202208185

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9826153/
https://www.ncbi.nlm.nih.gov/pubmed/36040131
http://dx.doi.org/10.1002/anie.202208185

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