Charge‐Transfer Transitions Govern the Reactivity and Photophysics of Vicinally Diphosphanyl‐Substituted Diborapentacenes

2,3‐Difluoro‐5,14‐dihydro‐5,14‐diborapentacene (DBP) was endowed with two vicinal Ph(2)P groups by an S(N)Ar reaction at both CF sites using Ph(2)PSiMe(3). Computations reveal the ambipolar product P to undergo P‐to‐B charge transfer under ambient light irradiation. Consequently, P is prone to photo...

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Detalles Bibliográficos
Autores principales: Jin, Tao, Bolte, Michael, Lerner, Hans‐Wolfram, Mewes, Jan‐Michael, Wagner, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9826252/
https://www.ncbi.nlm.nih.gov/pubmed/36094675
http://dx.doi.org/10.1002/chem.202202234

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9826252/
https://www.ncbi.nlm.nih.gov/pubmed/36094675
http://dx.doi.org/10.1002/chem.202202234

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