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Introducing the Perfluorinated Cp* Ligand into Coordination Chemistry

The reaction of AgBF(4) and [Rh(COD)Cl](2) (COD=1,5‐cyclooctadiene) in presence of [NEt(4)][C(5)(CF(3))(5)] afforded the fluorocarbon soluble complex [Rh(COD)(C(5)(CF(3))(5))] by salt metathesis. This complex represents the first example for a successful coordination of the weakly basic [C(5)(CF(3))...

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Detalles Bibliográficos
Autores principales: Sievers, Robin, Sellin, Malte, Rupf, Susanne M., Parche, Joshua, Malischewski, Moritz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9826324/
https://www.ncbi.nlm.nih.gov/pubmed/35984742
http://dx.doi.org/10.1002/anie.202211147