Pas de Deux of an NO Couple: Synchronous Photoswitching from a Double‐Linear to a Double‐Bent Ru(NO)(2) Core under Nitrosyl Charge Conservation

The {Ru(NO)(2)}(10) dinitrosylruthenium complex [Ru(NO)(2)(PPh(3))(2)] (1) shows photo‐induced linkage isomerism (PLI) of a special kind: the two NO ligands switch, on photo‐excitation, synchronously from the ground state (GS) with two almost linear RuNO functions to a metastable state (MS) which pe...

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Detalles Bibliográficos
Autores principales: Hasil, Asma, Beck, Daniel, Schröder, Daniel, Pillet, Sébastien, Wenger, Emmanuel, Woike, Theo, Klüfers, Peter, Schaniel, Dominik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9826364/
https://www.ncbi.nlm.nih.gov/pubmed/35983847
http://dx.doi.org/10.1002/anie.202210671

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9826364/
https://www.ncbi.nlm.nih.gov/pubmed/35983847
http://dx.doi.org/10.1002/anie.202210671

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