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Pas de Deux of an NO Couple: Synchronous Photoswitching from a Double‐Linear to a Double‐Bent Ru(NO)(2) Core under Nitrosyl Charge Conservation
The {Ru(NO)(2)}(10) dinitrosylruthenium complex [Ru(NO)(2)(PPh(3))(2)] (1) shows photo‐induced linkage isomerism (PLI) of a special kind: the two NO ligands switch, on photo‐excitation, synchronously from the ground state (GS) with two almost linear RuNO functions to a metastable state (MS) which pe...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9826364/ https://www.ncbi.nlm.nih.gov/pubmed/35983847 http://dx.doi.org/10.1002/anie.202210671 |