Light‐Driven Hydrodefluorination of Electron‐Rich Aryl Fluorides by an Anionic Rhodium‐Gallium Photoredox Catalyst

An anionic Rh−Ga complex catalyzed the hydrodefluorination of challenging C−F bonds in electron‐rich aryl fluorides and trifluoromethylarenes when irradiated with violet light in the presence of H(2), a stoichiometric alkoxide base, and a crown‐ether additive. Based on theoretical calculations, the...

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Detalles Bibliográficos
Autores principales: Moore, James T., Dorantes, Michael J., Pengmei, Zihan, Schwartz, Timothy M., Schaffner, Jacob, Apps, Samantha L., Gaggioli, Carlo A., Das, Ujjal, Gagliardi, Laura, Blank, David A., Lu, Connie C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9826370/
https://www.ncbi.nlm.nih.gov/pubmed/36017770
http://dx.doi.org/10.1002/anie.202205575

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9826370/
https://www.ncbi.nlm.nih.gov/pubmed/36017770
http://dx.doi.org/10.1002/anie.202205575

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