Quantum Interference in Mixed‐Valence Complexes: Tuning Electronic Coupling Through Substituent Effects

Whilst 2‐ or 5‐OMe groups on the bridging phenylene ring in [{Cp*(dppe)RuC≡C}(2)(μ‐1,3‐C(6)H(4))](+) have little influence on the electronic structure of this weakly coupled mixed‐valence complex, a 4‐OMe substituent enhances ground state electron delocalization, and increases the intensity of the I...

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Detalles Bibliográficos
Autores principales: Harrison, Daniel P., Grotjahn, Robin, Naher, Masnun, Ghazvini, Seyed M. B. H., Mazzucato, Daniel M., Korb, Marcus, Moggach, Stephen A., Lambert, Colin, Kaupp, Martin, Low, Paul J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828041/
https://www.ncbi.nlm.nih.gov/pubmed/36031588
http://dx.doi.org/10.1002/anie.202211000

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828041/
https://www.ncbi.nlm.nih.gov/pubmed/36031588
http://dx.doi.org/10.1002/anie.202211000

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