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Quantum Interference in Mixed‐Valence Complexes: Tuning Electronic Coupling Through Substituent Effects
Whilst 2‐ or 5‐OMe groups on the bridging phenylene ring in [{Cp*(dppe)RuC≡C}(2)(μ‐1,3‐C(6)H(4))](+) have little influence on the electronic structure of this weakly coupled mixed‐valence complex, a 4‐OMe substituent enhances ground state electron delocalization, and increases the intensity of the I...
| Autores principales: | , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828041/ https://www.ncbi.nlm.nih.gov/pubmed/36031588 http://dx.doi.org/10.1002/anie.202211000 |