Dimorpholinoacetylene and Its Use for the Synthesis of Tetraaminocyclobutadiene Species

The new diaminoacetylene (DAA) dimorpholinoacetylene (3) was prepared from 1,1‐dimorpholinoethene (1) by bromination to form the dibromoketene aminal 2, which upon lithiation afforded 3 through a Fritsch‐Buttenberg‐Wiechell rearrangement. Heating 3 at elevated temperatures resulted in a complete con...

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Detalles Bibliográficos
Autores principales: Körner, Lukas, Ho, Luong Phong, Puchta, Ralph, Stanger, Amnon, Tamm, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828195/
https://www.ncbi.nlm.nih.gov/pubmed/36148808
http://dx.doi.org/10.1002/chem.202202737

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828195/
https://www.ncbi.nlm.nih.gov/pubmed/36148808
http://dx.doi.org/10.1002/chem.202202737

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