Switchable Metal Sites in Metal–Organic Framework MFM‐300(Sc): Lewis Acid Catalysis Driven by Metal–Hemilabile Linker Bond Dynamics

Uncommon reversible guest‐induced metal‐hemilabile linker bond dynamics in MOF MFM‐300(Sc) was unraveled to switch on/switch off catalytic open metal sites. The catalytic activity of this MOF with non‐permanent open metal sites was demonstrated using a model Strecker hydrocyanation reaction as a pro...

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Detalles Bibliográficos
Autores principales: Peralta, Ricardo A., Lyu, Pengbo, López‐Olvera, Alfredo, Obeso, Juan L., Leyva, Carolina, Jeong, Nak Cheon, Ibarra, Ilich A., Maurin, Guillaume
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828200/
https://www.ncbi.nlm.nih.gov/pubmed/36165854
http://dx.doi.org/10.1002/anie.202210857

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828200/
https://www.ncbi.nlm.nih.gov/pubmed/36165854
http://dx.doi.org/10.1002/anie.202210857

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