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Taming Heavier Group 14 Imine Analogues: Accessing Tin Nitrogen [Sn=N] Double Bonds and their Cycloaddition/Metathesis Chemistry
A systematic study to access stable stannaimines is reported, by combining different heteroleptic stannylenes with a range of organic azides. The reactions of terphenyl‐/hypersilyl‐substituted stannylenes yield the putative tin nitrogen double bond, but is directly followed by 1,2‐silyl migration to...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828258/ https://www.ncbi.nlm.nih.gov/pubmed/36161749 http://dx.doi.org/10.1002/anie.202211616 |