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Taming Heavier Group 14 Imine Analogues: Accessing Tin Nitrogen [Sn=N] Double Bonds and their Cycloaddition/Metathesis Chemistry

A systematic study to access stable stannaimines is reported, by combining different heteroleptic stannylenes with a range of organic azides. The reactions of terphenyl‐/hypersilyl‐substituted stannylenes yield the putative tin nitrogen double bond, but is directly followed by 1,2‐silyl migration to...

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Detalles Bibliográficos
Autores principales: Fischer, Malte, Roy, Matthew M. D., Wales, Lewis. L., Ellwanger, Mathias A., McManus, Caitilin, Roper, Aisling F., Heilmann, Andreas, Aldridge, Simon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828258/
https://www.ncbi.nlm.nih.gov/pubmed/36161749
http://dx.doi.org/10.1002/anie.202211616