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C−H Activation of Inert Arenes using a Photochemically Activated Guanidinato‐Magnesium(I) Compound

UV irradiation of solutions of a guanidinate coordinated dimagnesium(I) compound, [{(Priso)Mg}(2)] 3 (Priso=[(DipN)(2)CNPr( i ) (2)](−), Dip=2,6‐diisopropylphenyl), in either benzene, toluene, the three isomers of xylene, or mesitylene, leads to facile activation of an aromatic C−H bond of the solve...

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Detalles Bibliográficos
Autores principales: Mullins, Jeremy C., Yuvaraj, K., Jiang, Yixiao, Van Trieste, Gerard P., Maity, Asim, Powers, David C., Jones, Cameron
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828268/
https://www.ncbi.nlm.nih.gov/pubmed/36017712
http://dx.doi.org/10.1002/chem.202202103