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Perfectly Isotactic Polypropylene upon In Situ Activation of Ultrarigid meso Hafnocenes

For more than 40 years, the synthesis of C (2)‐symmetric indenyl‐based racemic metallocenes for the isoselective polymerization of propylene relied on a tedious separation of the produced rac and meso isomers. Status quo, latter are considered wasteful as they produce atactic polypropylene (aPP) rat...

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Detalles Bibliográficos
Autores principales: Stieglitz, Lucas, Lenz, Tim M., Saurwein, Andreas, Rieger, Bernhard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828379/
https://www.ncbi.nlm.nih.gov/pubmed/36125844
http://dx.doi.org/10.1002/anie.202210797