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Tris(ortho‐carboranyl)borane: An Isolable, Halogen‐Free, Lewis Superacid
The synthesis of tris(ortho‐carboranyl)borane (BoCb(3)), a single site neutral Lewis superacid, in one pot from commercially available materials is achieved. The high fluoride ion affinity (FIA) confirms its classification as a Lewis superacid and the Gutmann‐Beckett method as well as adducts with L...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828388/ https://www.ncbi.nlm.nih.gov/pubmed/36135949 http://dx.doi.org/10.1002/anie.202212073 |