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Tris(ortho‐carboranyl)borane: An Isolable, Halogen‐Free, Lewis Superacid

The synthesis of tris(ortho‐carboranyl)borane (BoCb(3)), a single site neutral Lewis superacid, in one pot from commercially available materials is achieved. The high fluoride ion affinity (FIA) confirms its classification as a Lewis superacid and the Gutmann‐Beckett method as well as adducts with L...

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Detalles Bibliográficos
Autores principales: Akram, Manjur O., Tidwell, John R., Dutton, Jason L., Martin, Caleb D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828388/
https://www.ncbi.nlm.nih.gov/pubmed/36135949
http://dx.doi.org/10.1002/anie.202212073