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Electronic Materials: An Antiaromatic Propeller Made from the Four‐Fold Fusion of Tetraoxa[8]circulene and Perylene Diimides

The synthesis of an antiaromatic tetraoxa[8]circulene annulated with four perylene diimides (PDI), giving a dynamic non‐planar π‐conjugated system, is described. The molecule contains 32 aromatic rings surrounding one formally antiaromatic planarized cyclooctatetraene (COT). The intense absorption (...

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Detalles Bibliográficos
Autores principales: Pedersen, Viktor B. R., Pedersen, Stephan K., Jin, Zexin, Kofod, Nicolaj, Laursen, Bo W., Baryshnikov, Glib V., Nuckolls, Colin, Pittelkow, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828547/
https://www.ncbi.nlm.nih.gov/pubmed/36173989
http://dx.doi.org/10.1002/anie.202212293