Palladium‐Catalyzed PIDA‐Mediated δ‐C(sp(3))−H Acetoxylation of Amino Acid Derivatives: Overriding Competitive Intramolecular Amination

The selective δ‐C(sp(3))−H acetoxylation of N‐(SO(2)Py)‐protected amino acid derivatives has been accomplished by using palladium‐catalysis and PhI(OAc)(2) (PIDA) as both terminal oxidant and acetoxy source. The distinct structural and electronic features of the SO(2)Py compared to more traditional...

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Detalles Bibliográficos
Autores principales: Martínez‐Mingo, Mario, García‐Viada, Andrés, Prendes, Daniel Sowa, Alonso, Inés, Rodríguez, Nuria, Arrayás, Ramón Gómez, Carretero, Juan C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828559/
https://www.ncbi.nlm.nih.gov/pubmed/36177787
http://dx.doi.org/10.1002/anie.202209865

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828559/
https://www.ncbi.nlm.nih.gov/pubmed/36177787
http://dx.doi.org/10.1002/anie.202209865

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