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Stimuli Responsive Silylene: Electromerism Induced Reversible Switching Between Mono‐ and Bis‐Silylene

Electromerism is a very well‐known phenomenon in transition metal chemistry. In main group chemistry, this concept has only started getting attention recently. We report stimuli responsive low‐valent silicon compounds exhibiting electromerism. A mixed‐valent silaiminyl‐silylene 1, [LSi−Si(NDipp)L] (...

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Detalles Bibliográficos
Autores principales: Yadav, Ravi, Sun, Xiaofei, Köppe, Ralf, Gamer, Michael T., Weigend, Florian, Roesky, Peter W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828679/
https://www.ncbi.nlm.nih.gov/pubmed/36161745
http://dx.doi.org/10.1002/anie.202211115