Strain‐Release Pentafluorosulfanylation and Tetrafluoro(aryl)sulfanylation of [1.1.1]Propellane: Reactivity and Structural Insight

We leveraged the recent increase in synthetic accessibility of SF(5)Cl and Ar−SF(4)Cl compounds to combine chemistry of the SF(5) and SF(4)Ar groups with strain‐release functionalization. By effectively adding SF(5) and SF(4)Ar radicals across [1.1.1]propellane, we accessed structurally unique bicyc...

Descripción completa

Detalles Bibliográficos
Autores principales: Kraemer, Yannick, Ghiazza, Clément, Ragan, Abbey N., Ni, Shengyang, Lutz, Sigrid, Neumann, Elizabeth K., Fettinger, James C., Nöthling, Nils, Goddard, Richard, Cornella, Josep, Pitts, Cody Ross
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828730/
https://www.ncbi.nlm.nih.gov/pubmed/36137228
http://dx.doi.org/10.1002/anie.202211892

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828730/
https://www.ncbi.nlm.nih.gov/pubmed/36137228
http://dx.doi.org/10.1002/anie.202211892

Ejemplares similares