Chiral Bismuth‐Rhodium Paddlewheel Complexes Empowered by London Dispersion: The C−H Functionalization Nexus

Heterobimetallic [BiRh] tetracarboxylate catalysts endowed with 1,3‐disilylated phenylglycine paddlewheels benefit from interligand London dispersion. They were originally designed for asymmetric cyclopropanation but are now shown to perform very well in asymmetric C−H functionalization reactions to...

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Detalles Bibliográficos
Autores principales: Buchsteiner, Michael, Singha, Santanu, Decaens, Jonathan, Fürstner, Alois
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828831/
https://www.ncbi.nlm.nih.gov/pubmed/36102180
http://dx.doi.org/10.1002/anie.202212546

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828831/
https://www.ncbi.nlm.nih.gov/pubmed/36102180
http://dx.doi.org/10.1002/anie.202212546

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