Branching mechanism of photoswitching in an Fe(II) polypyridyl complex explained by full singlet-triplet-quintet dynamics

It has long been known that irradiation with visible light converts Fe(II) polypyridines from their low-spin (singlet) to high-spin (quintet) state, yet mechanistic interpretation of the photorelaxation remains controversial. Herein, we simulate the full singlet-triplet-quintet dynamics of the [Fe(t...

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Detalles Bibliográficos
Autores principales: Rozgonyi, Tamás, Vankó, György, Pápai, Mátyás
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9829715/
https://www.ncbi.nlm.nih.gov/pubmed/36697805
http://dx.doi.org/10.1038/s42004-022-00796-z

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9829715/
https://www.ncbi.nlm.nih.gov/pubmed/36697805
http://dx.doi.org/10.1038/s42004-022-00796-z

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