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2D conjugated microporous polyacetylenes synthesized via halogen-bond-assisted radical solid-phase polymerization for high-performance metal-ion absorbents
The paper reports the first free-radical solid-phase polymerization (SPP) of acetylenes. Acetylene monomers were co-crystalized using halogen bonding, and the obtained cocrystals were polymerized. Notably, because of the alignment of acetylene monomers in the cocrystals, the adjacent C≡C groups were...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9837052/ https://www.ncbi.nlm.nih.gov/pubmed/36635286 http://dx.doi.org/10.1038/s41467-023-35809-5 |