Photochemical Organocatalytic Functionalization of Pyridines via Pyridinyl Radicals

[Image: see text] We report a photochemical method for the functionalization of pyridines with radicals derived from allylic C–H bonds. Overall, two substrates undergo C–H functionalization to form a new C(sp(2))–C(sp(3)) bond. The chemistry harnesses the unique reactivity of pyridinyl radicals, gen...

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Detalles Bibliográficos
Autores principales: Le Saux, Emilien, Georgiou, Eleni, Dmitriev, Igor A., Hartley, Will C., Melchiorre, Paolo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9837848/
https://www.ncbi.nlm.nih.gov/pubmed/36574031
http://dx.doi.org/10.1021/jacs.2c12466

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9837848/
https://www.ncbi.nlm.nih.gov/pubmed/36574031
http://dx.doi.org/10.1021/jacs.2c12466

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