Cargando…
Photochemical Organocatalytic Functionalization of Pyridines via Pyridinyl Radicals
[Image: see text] We report a photochemical method for the functionalization of pyridines with radicals derived from allylic C–H bonds. Overall, two substrates undergo C–H functionalization to form a new C(sp(2))–C(sp(3)) bond. The chemistry harnesses the unique reactivity of pyridinyl radicals, gen...
Autores principales: | Le Saux, Emilien, Georgiou, Eleni, Dmitriev, Igor A., Hartley, Will C., Melchiorre, Paolo |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9837848/ https://www.ncbi.nlm.nih.gov/pubmed/36574031 http://dx.doi.org/10.1021/jacs.2c12466 |
Ejemplares similares
-
A General Organocatalytic System for Enantioselective Radical Conjugate Additions to Enals
por: Le Saux, Emilien, et al.
Publicado: (2021) -
A Photochemical Organocatalytic Strategy for the α‐Alkylation of Ketones by using Radicals
por: Spinnato, Davide, et al.
Publicado: (2020) -
Stereocontrolled Synthesis of 1,4‐Dicarbonyl Compounds by Photochemical Organocatalytic Acyl Radical Addition to Enals
por: Goti, Giulio, et al.
Publicado: (2018) -
Photochemical Organocatalytic Regio‐ and Enantioselective Conjugate Addition of Allyl Groups to Enals
por: Berger, Martin, et al.
Publicado: (2021) -
Enantioselective Organocatalytic Diels–Alder Trapping of Photochemically Generated Hydroxy‐o‐Quinodimethanes
por: Dell'Amico, Luca, et al.
Publicado: (2016)