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Binding Energy and Diffusion Barrier of Formic Acid on Pd(111)
[Image: see text] Velocity-resolved kinetics is used to measure the thermal rate of formic acid desorption from Pd(111) between 228 and 273 K for four isotopologues: HCOOH, HCOOD, DCOOH, DCOOD. Upon molecular adsorption, formic acid undergoes decomposition to CO(2) and H(2) and thermal desorption. T...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9841570/ https://www.ncbi.nlm.nih.gov/pubmed/36583672 http://dx.doi.org/10.1021/acs.jpca.2c07414 |