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Binding Energy and Diffusion Barrier of Formic Acid on Pd(111)

[Image: see text] Velocity-resolved kinetics is used to measure the thermal rate of formic acid desorption from Pd(111) between 228 and 273 K for four isotopologues: HCOOH, HCOOD, DCOOH, DCOOD. Upon molecular adsorption, formic acid undergoes decomposition to CO(2) and H(2) and thermal desorption. T...

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Detalles Bibliográficos
Autores principales: Fingerhut, Jan, Lecroart, Loïc, Borodin, Dmitriy, Schwarzer, Michael, Hörandl, Stefan, Kandratsenka, Alexander, Auerbach, Daniel J., Wodtke, Alec M., Kitsopoulos, Theofanis N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9841570/
https://www.ncbi.nlm.nih.gov/pubmed/36583672
http://dx.doi.org/10.1021/acs.jpca.2c07414