Cargando…

Binding Energy and Diffusion Barrier of Formic Acid on Pd(111)

[Image: see text] Velocity-resolved kinetics is used to measure the thermal rate of formic acid desorption from Pd(111) between 228 and 273 K for four isotopologues: HCOOH, HCOOD, DCOOH, DCOOD. Upon molecular adsorption, formic acid undergoes decomposition to CO(2) and H(2) and thermal desorption. T...

Descripción completa

Detalles Bibliográficos
Autores principales:	Fingerhut, Jan, Lecroart, Loïc, Borodin, Dmitriy, Schwarzer, Michael, Hörandl, Stefan, Kandratsenka, Alexander, Auerbach, Daniel J., Wodtke, Alec M., Kitsopoulos, Theofanis N.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2022
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9841570/ https://www.ncbi.nlm.nih.gov/pubmed/36583672 http://dx.doi.org/10.1021/acs.jpca.2c07414

Ejemplares similares

Steric Hindrance of NH(3) Diffusion on Pt(111) by Co-Adsorbed O-Atoms
por: Borodin, Dmitriy, et al.
Publicado: (2022)

NO Binding Energies to and Diffusion Barrier on Pd Obtained with Velocity-Resolved Kinetics
por: Borodin, Dmitriy, et al.
Publicado: (2021)

Kinetics of NH(3) Desorption and Diffusion on Pt: Implications for the Ostwald Process
por: Borodin, Dmitriy, et al.
Publicado: (2021)

Adsorption and Absorption Energies of Hydrogen with Palladium
por: Schwarzer, Michael, et al.
Publicado: (2022)

Measuring Transient Reaction Rates from Nonstationary Catalysts
por: Borodin, Dmitriy, et al.
Publicado: (2020)

Random Force in Molecular Dynamics with Electronic Friction
por: Hertl, Nils, et al.
Publicado: (2021)

Tuning reactivity layer-by-layer: formic acid activation on Ag/Pd(111)
por: Karatok, Mustafa, et al.
Publicado: (2020)

Highly Rotationally Excited N(2) Reveals Transition-State Character in the Thermal Decomposition of N(2)O on Pd(110)
por: Quan, Jiamei, et al.
Publicado: (2023)

Effective medium theory for bcc metals: electronically non-adiabatic H atom scattering in full dimensions
por: Hertl, Nils, et al.
Publicado: (2022)

Inelastic Scattering of H Atoms from Surfaces
por: Bünermann, Oliver, et al.
Publicado: (2021)

Multibounce and Subsurface Scattering of H Atoms Colliding with a van der Waals Solid
por: Hertl, Nils, et al.
Publicado: (2021)

Condensed-phase isomerization through tunnelling gateways
por: Choudhury, Arnab, et al.
Publicado: (2022)

H atom scattering from W(110): A benchmark for molecular dynamics with electronic friction.
por: Martin-Barrios, Raidel, et al.
Publicado: (2022)

Adsorption sites and diffusion steps of In and Cd on Pd(111) surfaces
por: Hunger, E, et al.
Publicado: (1990)

Mechanistic effects of blending formic acid with ethanol on Pd activity towards formic acid oxidation in acidic media
por: Al Najjar, Taher, et al.
Publicado: (2021)

Hyperthermal velocity distributions of recombinatively-desorbing oxygen from Ag(111)
por: Dorst, Arved C., et al.
Publicado: (2023)

3D-nanoarchitectured Pd/Ni catalysts prepared by atomic layer deposition for the electrooxidation of formic acid
por: Assaud, Loïc, et al.
Publicado: (2014)

The Catalytic Reactivity of Alloys; Ethanol and Formic Acid Decomposition on Cu–Pd(110)
por: Bowker, Michael, et al.
Publicado: (2022)

Photo-enhanced dehydrogenation of formic acid on Pd-based hybrid plasmonic nanostructures
por: Zhu, Jiannan, et al.
Publicado: (2023)

Adsorption sites of $^{111}$In and $^{111m}$Cd on Pd(111) surfaces characterized by the electric field gradient
por: Hunger, E, et al.
Publicado: (1990)

A Facile Preparation of Sandwich-Structured Pd/Polypyrrole-Graphene/Pd Catalysts for Formic Acid Electro-Oxidation
por: Lu, Zhenjiang, et al.
Publicado: (2023)

MWCNT-Supported PVP-Capped Pd Nanoparticles as Efficient Catalysts for the Dehydrogenation of Formic Acid
por: Ortega-Murcia, Alejandro, et al.
Publicado: (2020)

Enhanced Formic Acid Oxidation over SnO(2)-decorated Pd Nanocubes
por: Rettenmaier, Clara, et al.
Publicado: (2020)

Pd-C Catalytic Thin Films Prepared by Magnetron Sputtering for the Decomposition of Formic Acid
por: Arzac, Gisela Mariana, et al.
Publicado: (2021)

Porous three-dimensional network of Pd–Cu aerogel toward formic acid oxidation
por: Douk, Abdollatif Shafaei, et al.
Publicado: (2018)

Notes on Formic Aldehyde
por: Howe, J. Morgan
Publicado: (1896)

Spin-Forbidden Carbon–Carbon Bond Formation in Vibrationally Excited α-CO
por: DeVine, Jessalyn A., et al.
Publicado: (2022)

Anchoring Pd-nanoparticles on dithiocarbamate- functionalized SBA-15 for hydrogen generation from formic acid
por: Farajzadeh, Mustafa, et al.
Publicado: (2020)

TiO(2) Nanotubes with Pt and Pd Nanoparticles as Catalysts for Electro-Oxidation of Formic Acid
por: Pisarek, Marcin, et al.
Publicado: (2020)

Facile Synthesis of Unsupported Pd Aerogel for High Performance Formic Acid Microfluidic Fuel Cell
por: Martínez-Lázaro, Alejandra, et al.
Publicado: (2022)

Disclosing the leaching behaviour of Pd@CMK3 catalysts in formic acid decomposition by electron tomography
por: Huang, Xiaohui, et al.
Publicado: (2023)

Formic and Acetic Acids as Poisons
por: Karunakaran, Rajyasevanirata C. O., et al.
Publicado: (1944)

Au/Pd core-shell nanoparticles with varied hollow Au cores for enhanced formic acid oxidation
por: Hsu, Chiajen, et al.
Publicado: (2013)

One-Pot Synthesis of Graphene-Supported Monodisperse Pd Nanoparticles as Catalyst for Formic Acid Electro-oxidation
por: Yang, Sudong, et al.
Publicado: (2014)

Facile Synthesis of Pd Nanocubes with Assistant of Iodide and Investigation of Their Electrocatalytic Performances Towards Formic Acid Oxidation
por: Liu, Xuan, et al.
Publicado: (2019)

Clean Electrochemical Synthesis of Pd–Pt Bimetallic Dendrites with High Electrocatalytic Performance for the Oxidation of Formic Acid
por: Liu, Jie, et al.
Publicado: (2022)

Effect of thermal treatment of Pd decorated Fe/C nanocatalysts on their catalytic performance for formic acid oxidation
por: Li, Weiping, et al.
Publicado: (2018)

Formic Acid Dehydrogenation over Ru- and Pd-Based Catalysts: Gas- vs. Liquid-Phase Reactions
por: Ruiz-López, Estela, et al.
Publicado: (2023)

Pd(3)Co(1) Alloy Nanocluster on the MWCNT Catalyst for Efficient Formic Acid Electro-Oxidation
por: Yang, Pingping, et al.
Publicado: (2022)

Pronounced effect of yttrium oxide on the activity of Pd/rGO electrocatalyst for formic acid oxidation reaction
por: Sofian, Muhammad, et al.
Publicado: (2023)

Cannot write session to /tmp/vufind_sessions/sess_k3i71ieqmt36fqtjg0seqpopf6