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High-Pressure Crystallization and Thermodynamic Stability Study on the Resolution of High-Density Enantiomers from Low-Density Racemates
[Image: see text] High-pressure recrystallization could be the cheapest clean method of resolving enantiomers from the racemates defying Wallach’s rule. We have investigated the effect of pressure on sodium tartrate monohydrate (NaTa·H(2)O), a notorious exception from Wallach’s rule: both racemic po...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9841603/ https://www.ncbi.nlm.nih.gov/pubmed/36598359 http://dx.doi.org/10.1021/acs.orglett.2c03747 |