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High-Pressure Crystallization and Thermodynamic Stability Study on the Resolution of High-Density Enantiomers from Low-Density Racemates

[Image: see text] High-pressure recrystallization could be the cheapest clean method of resolving enantiomers from the racemates defying Wallach’s rule. We have investigated the effect of pressure on sodium tartrate monohydrate (NaTa·H(2)O), a notorious exception from Wallach’s rule: both racemic po...

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Detalles Bibliográficos
Autores principales: Roszak, Kinga, Katrusiak, Andrzej
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9841603/
https://www.ncbi.nlm.nih.gov/pubmed/36598359
http://dx.doi.org/10.1021/acs.orglett.2c03747