Reactions of diphosphine-stabilized Os(3) clusters with triphenylantimony: syntheses and structures of new antimony-containing Os(3) clusters via Sb–Ph bond cleavage

The reactivity of the trimetallic clusters [Os(3)(CO)(10)(μ-dppm)] [dppm = bis(diphenylphosphino)methane] and [HOs(3)(CO)(8){μ(3)-Ph(2)PCH(2)PPh(C(6)H(4)-μ(2),σ(1))}] with triphenylantimony (SbPh(3)) has been examined. [Os(3)(CO)(10)(μ-dppm)] reacts with SbPh(3) in refluxing toluene to yield three n...

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Detalles Bibliográficos
Autores principales: Islam, Fahmida, Hasan, Md. Sohag, Ghosh, Shishir, Richmond, Michael G., Kabir, Shariff E., Roesky, Herbert W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9845985/
https://www.ncbi.nlm.nih.gov/pubmed/36756440
http://dx.doi.org/10.1039/d2ra07284j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9845985/
https://www.ncbi.nlm.nih.gov/pubmed/36756440
http://dx.doi.org/10.1039/d2ra07284j

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