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Reactions of diphosphine-stabilized Os(3) clusters with triphenylantimony: syntheses and structures of new antimony-containing Os(3) clusters via Sb–Ph bond cleavage
The reactivity of the trimetallic clusters [Os(3)(CO)(10)(μ-dppm)] [dppm = bis(diphenylphosphino)methane] and [HOs(3)(CO)(8){μ(3)-Ph(2)PCH(2)PPh(C(6)H(4)-μ(2),σ(1))}] with triphenylantimony (SbPh(3)) has been examined. [Os(3)(CO)(10)(μ-dppm)] reacts with SbPh(3) in refluxing toluene to yield three n...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9845985/ https://www.ncbi.nlm.nih.gov/pubmed/36756440 http://dx.doi.org/10.1039/d2ra07284j |