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Mechanochemical protocol facilitates the generation of arylmanganese nucleophiles from unactivated manganese metal

The direct synthesis of organomanganese reagents from organic halides and manganese metal remains a challenge. Current solution-based approaches require the preparation of activated manganese (Rieke manganese) or the use of multiple metal additives to promote the insertion of manganese metal into a...

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Detalles Bibliográficos
Autores principales: Takahashi, Rina, Gao, Pan, Kubota, Koji, Ito, Hajime
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9847654/
https://www.ncbi.nlm.nih.gov/pubmed/36741531
http://dx.doi.org/10.1039/d2sc05468j