Heavy metalla vinyl-cations show metal–Lewis acid cooperativity in reaction with small molecules (NH(3), N(2)H(4), H(2)O, H(2))

Halide abstraction from tetrylidene complexes [TbbE(Br)IrH(PMe(3))(3)] [E = Ge (1), Sn (2)] and [Ar*E(Cl)IrH(PMe(3))(3)] gives the salts [TbbEIrH(PMe(3))(3)][BAr(F)(4)] [E = Ge (3), Sn (4)] and [Ar*EIrH(PMe(3))(3)][BAr(F)(4)] [E = Ge (3′), E = Sn (4′)] (Tbb = 2,6-[CH(SiMe(3))(2)](2)-4-(t-Bu)C(6)H(2)...

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Detalles Bibliográficos
Autores principales: Auer, Maximilian, Bolten, Janina, Eichele, Klaus, Schubert, Hartmut, Sindlinger, Christian P., Wesemann, Lars
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9847682/
https://www.ncbi.nlm.nih.gov/pubmed/36741530
http://dx.doi.org/10.1039/d2sc05620h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9847682/
https://www.ncbi.nlm.nih.gov/pubmed/36741530
http://dx.doi.org/10.1039/d2sc05620h

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