Photo-on-Demand In Situ Synthesis of N-Substituted Trichloroacetamides with Tetrachloroethylene and Their Conversions to Ureas, Carbamates, and Polyurethanes

[Image: see text] N-substituted trichloroacetamides (NTCAs), which serve as blocked isocyanates, were synthesized in ∼97% yields by in situ photo-on-demand trichloroacetylation of amines with tetrachloroethylene (TCE). The reactions were performed by photo-irradiation of TCE solutions containing an...

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Detalles Bibliográficos
Autores principales: Akamatsu, Toshiki, Shele, Muge, Matsune, Ayako, Kashiki, Yoshiyuki, Liang, Fengying, Okazoe, Takashi, Tsuda, Akihiko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9851034/
https://www.ncbi.nlm.nih.gov/pubmed/36687089
http://dx.doi.org/10.1021/acsomega.2c07233

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9851034/
https://www.ncbi.nlm.nih.gov/pubmed/36687089
http://dx.doi.org/10.1021/acsomega.2c07233

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