Cargando…
Photo-on-Demand In Situ Synthesis of N-Substituted Trichloroacetamides with Tetrachloroethylene and Their Conversions to Ureas, Carbamates, and Polyurethanes
[Image: see text] N-substituted trichloroacetamides (NTCAs), which serve as blocked isocyanates, were synthesized in ∼97% yields by in situ photo-on-demand trichloroacetylation of amines with tetrachloroethylene (TCE). The reactions were performed by photo-irradiation of TCE solutions containing an...
Autores principales: | Akamatsu, Toshiki, Shele, Muge, Matsune, Ayako, Kashiki, Yoshiyuki, Liang, Fengying, Okazoe, Takashi, Tsuda, Akihiko |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9851034/ https://www.ncbi.nlm.nih.gov/pubmed/36687089 http://dx.doi.org/10.1021/acsomega.2c07233 |
Ejemplares similares
-
Photo-on-Demand Phosgenation Reactions with Chloroform
for Selective Syntheses of N-Substituted Ureas and Isocyanates
por: Muranaka, Ryo, et al.
Publicado: (2022) -
Photo-on-Demand In Situ Phosgenation
Reactions That Cross Three Phases of a Heterogeneous Solution of Chloroform
and Aqueous NaOH
por: Tsuda, Akihiko, et al.
Publicado: (2023) -
Upgrading
Polyurethanes into Functional Ureas through
the Asymmetric Chemical Deconstruction of Carbamates
por: Olazabal, Ion, et al.
Publicado: (2022) -
Photo-On-Demand
Synthesis of α-Amino
Acid N-Carboxyanhydrides with Chloroform
por: Sugimoto, Toshiyuki, et al.
Publicado: (2022) -
Indirect reduction of CO(2) and recycling of polymers by manganese-catalyzed transfer hydrogenation of amides, carbamates, urea derivatives, and polyurethanes
por: Liu, Xin, et al.
Publicado: (2021)