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Visible light mediated organocatalytic dehydrogenative aza-coupling of 1,3-diones using aryldiazonium salts

An efficient protocol for diazenylation of 1,3-diones under photoredox conditions is presented herein. C–N bond forming C(sp(3))–H functionalization of cyclic and alkyl diones by unstable aryl diazenyl radicals is achieved through reaction with aryldiazonium tetrafluoroborates by organocatalysts und...

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Detalles Bibliográficos
Autores principales: Das, Ramanand, Kundu, Taraknath, Basumatary, Joneswar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9853514/
https://www.ncbi.nlm.nih.gov/pubmed/36756411
http://dx.doi.org/10.1039/d2ra07807d