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Spontaneous Fe(III)/Fe(II) redox cycling in single-atom catalysts: Conjugation effect and electron delocalization
The mechanism of spontaneous Fe(III)/Fe(II) redox cycling in iron-centered single-atom catalysts (I-SACs) is often overlooked. Consequently, pathways for continuous SO(4)(·-)/HO⋅ generation during peroxymonosulfate (PMS) activation by I-SACs remain unclear. Herein, the evolution of the iron center a...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Elsevier
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9860487/ https://www.ncbi.nlm.nih.gov/pubmed/36691626 http://dx.doi.org/10.1016/j.isci.2022.105902 |