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Spontaneous Fe(III)/Fe(II) redox cycling in single-atom catalysts: Conjugation effect and electron delocalization

The mechanism of spontaneous Fe(III)/Fe(II) redox cycling in iron-centered single-atom catalysts (I-SACs) is often overlooked. Consequently, pathways for continuous SO(4)(·-)/HO⋅ generation during peroxymonosulfate (PMS) activation by I-SACs remain unclear. Herein, the evolution of the iron center a...

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Detalles Bibliográficos
Autores principales:	Qian, Zheng, Wang, Lingzhen, Dzakpasu, Mawuli, Tian, Yujia, Ding, Dahu, Chen, Rongzhi, Wang, Gen, Yang, Shengjiong
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Elsevier 2022
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9860487/ https://www.ncbi.nlm.nih.gov/pubmed/36691626 http://dx.doi.org/10.1016/j.isci.2022.105902

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