Reshuffle Bonds by Ball Milling: A Mechanochemical Protocol for Charge-Accelerated Aza-Claisen Rearrangements

This study presents the development of a mechanochemical protocol for a charge-accelerated aza-Claisen rearrangement. The protocol waives the use of commonly applied transition metals, ligands, or pyrophoric Lewis acids, e.g., AlMe(3). Based on (heterocyclic) tertiary allylamines and acyl chlorides,...

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Detalles Bibliográficos
Autores principales: Schumacher, Christian, Fritz, Lieselotte, Hanek, Lena M., Sidorin, Vitali, Brüx, Daniel, Bolm, Carsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9860570/
https://www.ncbi.nlm.nih.gov/pubmed/36677865
http://dx.doi.org/10.3390/molecules28020807

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9860570/
https://www.ncbi.nlm.nih.gov/pubmed/36677865
http://dx.doi.org/10.3390/molecules28020807

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