Spontaneous Transition of Alkyl Carbocations to Unsaturated Vinyl-Type Carbocations in Organic Solutions

It was found that alkyl carbocations, when their salts are dissolved in common organochlorine solvents, decompose to unsaturated vinyl-type carbocations that are stabler in solutions. This is a convenient method for obtaining salts of vinyl cations and their solutions for further research.

Detalles Bibliográficos
Autores principales: Stoyanov, Evgenii S., Stoyanova, Irina V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9860910/
https://www.ncbi.nlm.nih.gov/pubmed/36675316
http://dx.doi.org/10.3390/ijms24021802

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9860910/
https://www.ncbi.nlm.nih.gov/pubmed/36675316
http://dx.doi.org/10.3390/ijms24021802

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