Spontaneous Transition of Alkyl Carbocations to Unsaturated Vinyl-Type Carbocations in Organic Solutions

It was found that alkyl carbocations, when their salts are dissolved in common organochlorine solvents, decompose to unsaturated vinyl-type carbocations that are stabler in solutions. This is a convenient method for obtaining salts of vinyl cations and their solutions for further research.

Detalles Bibliográficos
Autores principales: Stoyanov, Evgenii S., Stoyanova, Irina V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9860910/
https://www.ncbi.nlm.nih.gov/pubmed/36675316
http://dx.doi.org/10.3390/ijms24021802
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author Stoyanov, Evgenii S.
Stoyanova, Irina V.
author_facet Stoyanov, Evgenii S.
Stoyanova, Irina V.
author_sort Stoyanov, Evgenii S.
collection PubMed
description It was found that alkyl carbocations, when their salts are dissolved in common organochlorine solvents, decompose to unsaturated vinyl-type carbocations that are stabler in solutions. This is a convenient method for obtaining salts of vinyl cations and their solutions for further research.
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spelling pubmed-98609102023-01-22 Spontaneous Transition of Alkyl Carbocations to Unsaturated Vinyl-Type Carbocations in Organic Solutions Stoyanov, Evgenii S. Stoyanova, Irina V. Int J Mol Sci Communication It was found that alkyl carbocations, when their salts are dissolved in common organochlorine solvents, decompose to unsaturated vinyl-type carbocations that are stabler in solutions. This is a convenient method for obtaining salts of vinyl cations and their solutions for further research. MDPI 2023-01-16 /pmc/articles/PMC9860910/ /pubmed/36675316 http://dx.doi.org/10.3390/ijms24021802 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Communication
Stoyanov, Evgenii S.
Stoyanova, Irina V.
Spontaneous Transition of Alkyl Carbocations to Unsaturated Vinyl-Type Carbocations in Organic Solutions
title Spontaneous Transition of Alkyl Carbocations to Unsaturated Vinyl-Type Carbocations in Organic Solutions
title_full Spontaneous Transition of Alkyl Carbocations to Unsaturated Vinyl-Type Carbocations in Organic Solutions
title_fullStr Spontaneous Transition of Alkyl Carbocations to Unsaturated Vinyl-Type Carbocations in Organic Solutions
title_full_unstemmed Spontaneous Transition of Alkyl Carbocations to Unsaturated Vinyl-Type Carbocations in Organic Solutions
title_short Spontaneous Transition of Alkyl Carbocations to Unsaturated Vinyl-Type Carbocations in Organic Solutions
title_sort spontaneous transition of alkyl carbocations to unsaturated vinyl-type carbocations in organic solutions
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9860910/
https://www.ncbi.nlm.nih.gov/pubmed/36675316
http://dx.doi.org/10.3390/ijms24021802
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