Theoretical Study of the Reaction Mechanism of Phenol–Epoxy Ring-Opening Reaction Using a Latent Hardening Accelerator and a Reactivity Evaluation by Substituents

The mechanism of the phenol–epoxide ring-opening reaction using tetraphenylphosphonium-tetraphenylborate (TPP-K) was investigated using the density functional theory (DFT) method. The reaction was initiated by breaking the P-B bond of TPP-K. The generated tetraphenylborate (TetraPB(−)) reacted with...

Descripción completa

Detalles Bibliográficos
Autores principales: Mitani, Ryusuke, Yamamoto, Hidetoshi, Sumimoto, Michinori
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9861531/
https://www.ncbi.nlm.nih.gov/pubmed/36677752
http://dx.doi.org/10.3390/molecules28020694

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9861531/
https://www.ncbi.nlm.nih.gov/pubmed/36677752
http://dx.doi.org/10.3390/molecules28020694

Ejemplares similares